Poly[(μ2-azido-κ2 N 1:N 1)[μ2-5-(8-quinolyloxymethyl)tetrazolato-κ4 N 1,O,N 5:N 4]zinc(II)]
نویسنده
چکیده
In the title compound, [Zn(C(11)H(8)N(5)O)(N(3))](n), the Zn atom is hexa-coordinated by five N atoms and one O atom in a distorted octa-hedral geometry. The chelating 5-(8-quinolyloxymeth-yl)tetra-zolate ligands are approximately planar, with a dihedral angle of 3.6 (2)° between the quinoline and tetra-zole planes. Adjacent Zn atoms are linked by two bridging azide ligands across a centre of inversion, and further coordination by one N atom of an adjacent tetra-zole unit forms two-dimensional frameworks in (100). C-H⋯N inter-actions exist between ligands in neighbouring layers.
منابع مشابه
Poly[(μ2-azido-κ2 N 1:N 1)[μ2-5-(8-quinolyloxymethyl)tetrazolato-κ4 N 1,O,N 5:N 4]manganese(II)]
In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexa-coordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octa-hedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinolyloxymeth-yl)tetra-zolate ligands in a μ(2)-η(1)(N),η(3)-(N,N,O) fashion to form a two-dimensional...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009